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Beilstein J. Org. Chem. 2019, 15, 3000–3008, doi:10.3762/bjoc.15.296
Graphical Abstract
Figure 1: Structures of azonium ions studied.
Figure 2: a) Structures of model compounds used for computations (see Experimental section; in calculations, ...
Scheme 1: Synthesis of bis(4-amino-2-bromo-6-methoxy)azobenzene compounds.
Figure 3: a) UV–vis spectra of 4 in DCM (ca. 15 µM) at the PSS and 440 nm irradiation (thick dotted line; ca....
Figure 4: a) UV–vis spectra of 5 in aqueous solution (c ≈ 15 µM, 5% methanol, pH 7) at the PSS and 440 nm irr...
Beilstein J. Org. Chem. 2012, 8, 2184–2190, doi:10.3762/bjoc.8.246
Scheme 1: Bisazobenzene derivatives.
Scheme 2: Synthetic route for the preparation of bisazobenzene derivative 2.
Figure 1: (a) Histograms showing the relative populations of conformations having the sulfur-to-sulfur distan...
Figure 2: (a) Normalized UV–vis absorption spectra of 2 in DMSO, acetonitrile, MeOH and sodium phosphate buff...
Figure 3: (a) Photoswitching of 2 with violet light (407–410 nm) at different temperatures (4, 10 and 20 °C) ...